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Konishi, Hiroyuki; Yamashita, Masato*; Uchida, Hitoshi*; Mizuki, Junichiro
Materials Transactions, 46(2), p.337 - 341, 2005/02
Times Cited Count：9 Percentile：57.22(Materials Science, Multidisciplinary)We have performed extended X-ray absorption fine structure (EXAFS) analysis for artificial Cr-goethite to elucidate the local structure around Cr in Cr-goethite. The spectra were obtained using synchrotron radiation X-rays at the Photon Factory in Tsukuba. The first shell contributions were isolated by Fourier filtering the EXAFS data, and the inverse Fourier transformed single-shell data were analyzed using curve fitting method. The results show that Cr is coordinated with (7
1) O
ions. The protective character of Cr-goethite protective rust layer on weathering steel can be interpreted in terms of the O coordination around Cr
resulting in creation of negative fixed-charge in the Cr-goethite particles.
Hama, Katsuhiro; Taniguchi, Naoki; Honda, Akira
JNC TN7430 2000-002, 25 Pages, 2001/01
JNC-TN7430-2000-002.pdf:3.32MB
The burial tests of mild steel and pure titanium were performed in a gallery at Tono mine to assess the corrosion resistance of these materials under goundwater environment. Specimens were placed in the container and immersed into groundwater. After the immersion period, the apperance of the surface of these specimens were observed. The corrosion product of mild steel specimen was analysed by various methods. The average corrosion rate of mild steel for 10 years was assessed by the measurement of the weight loss of carbon steel specimen. The results of the test were summerised as follows : (1)The average corrosion rate of mild steel for 10 years was assessed to be 4.36 
10
mm/y by the weight loss of the specimen. (2)The corrosion product consists of outer porous substance and inner tight corrosion product film. The former contains ferric oxide such as goethite and the latter contains ferrous oxide such as magnetite. (3)The evidence of the initiation of localised corrosion was not observed on the titanium specimens.
*; Nagano, Tetsushi; ; Muraoka, Susumu
JAERI-M 92-004, 12 Pages, 1992/02
no abstracts in English
